| # | Name | Verein | Geburtstag | ||
|---|---|---|---|---|---|
| Torwart | |||||
| 1 |  | Claudio Bravo |  | Manchester City | 13.04.1983 |
| 23 |  | Johnny Herrera |  | Universidad de Chile | 09.05.1981 |
| 12 |  | Cristopher Toselli |  | Universidad Católica | 15.06.1988 |
| Abwehr | |||||
| 15 |  | Jean Beausejour | | Universidad de Chile | 01.06.1984 |
| 13 |  | Paulo Díaz |  | San Lorenzo | 25.08.1994 |
| 4 |  | Mauricio Isla |  | Cagliari Calcio | 12.06.1988 |
| 18 |  | Gonzalo Jara | | Universidad de Chile | 29.08.1985 |
| 17 |  | Gary Medel |  | Inter Mailand | 03.08.1987 |
| 2 |  | Eugenio Mena |  | Sport Recife - PE | 18.07.1988 |
| 3 |  | Enzo Roco |  | Cruz Azul | 16.08.1992 |
| Mittelfeld | |||||
| 20 |  | Charles Aránguiz |  | Bayer Leverkusen | 17.04.1989 |
| 21 |  | Marcelo Díaz |  | RC Celta | 30.12.1986 |
| 6 |  | José Fuenzalida | | Universidad Católica | 22.02.1985 |
| 14 |  | Felipe Gutiérrez |  | Internacional | 08.10.1990 |
| 10 |  | Pablo Hernández | | RC Celta | 24.10.1986 |
| 16 |  | Martín Rodríguez | | Cruz Azul | 05.08.1994 |
| 5 |  | Francisco Silva | | Cruz Azul | 11.02.1986 |
| 19 |  | Leonardo Valencia |  | Palestino | 25.04.1991 |
| 8 |  | Arturo Vidal |  | Bayern München | 22.05.1987 |
| Sturm | |||||
| 22 |  | Edson Puch |  | Club Necaxa | 04.09.1986 |
| 9 |  | Ángelo Sagal |  | Huachipato | 18.04.1993 |
| 7 |  | Alexis Sánchez |  | Arsenal FC | 19.12.1988 |
| 11 |  | Eduardo Vargas |  | UANL Tigres | 20.11.1989 |
| Trainer | |||||
 | Juan Antonio Pizzi | 07.06.1968 | |||
| Co-Trainer | |||||
 | Nicolás Diez | 09.02.1977 | |||
| Torwart-Trainer | |||||
 | Martín Tocalli | 14.09.1973 | |||
